WHAT
IS FUEL ETHANOL
Ethanol (ethyl
alcohol, grain alcohol, ETOH) is a clear, colorless liquid
with a characteristic, agreeable odor. In dilute aqueous solution,
it has a somewhat sweet flavor, but in more concentrated solutions
it has a burning taste. Ethanol, CH3CH2OH, is an alcohol,
a group of chemical compounds whose molecules contain a hydroxyl
group, -OH, bonded to a carbon atom. The word alcohol derives
from Arabic al-kuhul, which denotes a fine powder of antimony
produced by distilling antimony and used as an eye makeup.
Alcohol originally referred to any fine powder, but medieval
alchemists later applied the term to the refined products
of distillation, and this led to the current usage.
Ethanol melts at -114.1°C, boils at 78.5°C, and has a density
of 0.789 g/mL at 20°C. Its low freezing point has made it
useful as the fluid in thermometers for temperatures below
-40°C, the freezing point of mercury, and for other low-temperature
purposes, such as for antifreeze in automobile radiators.
Ethanol has been made since ancient
times by the fermentation of sugars. All beverage ethanol
and more than half of industrial ethanol is still made by
this process. Simple sugars are the raw material. Zymase,
an enzyme from yeast, changes the simple sugars into ethanol
and carbon dioxide. The fermentation reaction, represented
by the simple equation C6H12O6 2 CH3CH2OH + 2 CO2 is actually
very complex, and impure cultures of yeast produce varying
amounts of other substances, including glycerine and various
organic acids. In the production of beverages, such as whiskey
and brandy, the impurities supply the flavor. Starches from
potatoes, corn, wheat, and other plants can also be used in
the production of ethanol by fermentation. However, the starches
must first be broken down into simple sugars. An enzyme released
by germinating barley, diastase, converts starches into sugars.
Thus, the germination of barley, called malting, is the first
step in brewing beer from starchy plants, such as corn and
wheat.
ETHANOL AS A FUEL
Ethanol is used as an automotive fuel
by itself and can be mixed with gasoline to form what has
been called "gasohol" FUEL ETHANOL- the most common blends contain 10%
ethanol and 85% ethanol mixed with gasoline. Over 1 billion
gallons of ethanol are blended with gasoline every year in
the United States. Because the ethanol molecule contains oxygen,
it allows the engine to more completely combust the fuel,
resulting in fewer emissions. Since ethanol is produced from
plants that harness the power of the sun, ethanol is also
considered a renewable fuel. Therefore, ethanol has many advantages
as an automotive fuel.
Most industrial ethanol is denatured
to prevent its use as a beverage. Denatured ethanol contains
small amounts, 1 or 2 percent each, of several different unpleasant
or poisonous substances. The removal of all these substances
would involve a series of treatments more expensive than the
federal excise tax on alcoholic beverages (currently about
$20 per gallon). These denaturants render ethanol unfit for
some industrial uses. In such industries undenatured ethanol
is used under close federal supervision.
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